Manganese?Catalyzed Hydroborations with Broad Scope
نویسندگان
چکیده
Reductive transformations of easily available oxidized matter are at the heart synthetic manipulation and chemical valorization. The applications catalytic hydrofunctionalization benefit from use liquid reducing agents operationally facile setups. Metal-catalyzed hydroborations provide a highly prolific platform for reductive valorizations stable C=X electrophiles. Here, we report an especially facile, broad-scope reduction various functions including carbonyls, carboxylates, pyridines, carbodiimides, carbonates under very mild conditions with inexpensive pre-catalyst Mn(hmds)2. reaction could be successfully applied to depolymerizations.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202103550